Light Emission Spectroscopy from Metal Electrodes during Electrolysis

• AZUMI Kazuhisa

  Graduate School of Engineering, Hokkaido University

• SEO Masahiro

  Graduate School of Engineering, Hokkaido University

• MIZUNO Tadahiko

  Graduate School of Engineering, Hokkaido University

Bibliographic Information

Other Title

• 各種金属電極からの電解発光スペクトルの解析
• カクシュ キンゾク デンキョク カラ ノ デンカイ ハッコウ スペクトル ノ カイセキ

Abstract

Light emission from the metal electrodes cathodically polarized at cell voltages up to 250 V was investigated in various aqueous electrolyte solutions. The light emission was observed when the temperature of electrodes exceeded the boiling temperature of the electrolyte due to the intense cathodic polarization: a thin vapor layer was formed at the metal/electrolyte interface in which a high electric field ionized vapor molecules to generate the plasma state. The light emission was caused by a glow discharge at relatively low cell voltages and by a spark discharge at high cell voltages. The spectra of the emitted light were assigned to the constituents of the electrolyte solution, electrode material and gaseous hydrogen evolved at the electrode.

Journal

• Electrochemistry

  Electrochemistry 67 (4), 349-354, 1999-04-05

  The Electrochemical Society of Japan

Keywords

• Plasma-electrochemistry
• Photo-spectroscopy
• Glow Discharge
• Spark Discharge

Details

• CRID: 1390564227346637312
• NII Article ID: 10002566886
• NII Book ID: AN00151637
• DOI: 10.5796/electrochemistry.67.349
• ISSN: 21862451
• ISSN: 13443542
• ISSN: http://id.crossref.org/issn/13443542
• NDL BIB ID: 4698457
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I4698457
• Web Site: https://www.jstage.jst.go.jp/article/electrochemistry/67/4/67_349/_pdf
• Text Lang: ja
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• Abstract License Flag: Allowed