Electrochemical Behavior of Vanadium Trichloride in 1-ethyl-3-methyimidazolium Chloride-Aluminum Trichloride Molten Salt
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- KATAYAMA Yasushi
- Department of Applied Chemistry, Faculty of Science and Technology, Keio University
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- KONISHIIKE Isamu
- Department of Applied Chemistry, Faculty of Science and Technology, Keio University
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- MIURA Takashi
- Department of Applied Chemistry, Faculty of Science and Technology, Keio University
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- KISHI Tomiya
- Department of Applied Chemistry, Faculty of Science and Technology, Keio University
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Abstract
<p>Electrochemical behavior of trivalent vanadium species was investigated in a Lewis basic 1-ethyl-3-methylimidazolium chloride (EMIC)-aluminum trichloride (AlCl3) molten salt at room temperature. The reduction of V(III) was observed around −1.2 V vs. Al(III)/Al in the cyclic voltammogram on platinum electrode. The reduction process of V(III) seems electrochemically irreversible as observed in aqueous solution.</p>
Journal
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- Electrochemistry
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Electrochemistry 67 (6), 547-549, 1999-06-05
The Electrochemical Society of Japan
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Details 詳細情報について
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- CRID
- 1390564227346889472
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- NII Article ID
- 10002567386
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- NII Book ID
- AN00151637
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- ISSN
- 21862451
- 13443542
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- NDL BIB ID
- 4740651
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- Text Lang
- en
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Allowed