Electrochemical Behavior of Vanadium Trichloride in 1-ethyl-3-methyimidazolium Chloride-Aluminum Trichloride Molten Salt

• KATAYAMA Yasushi

  Department of Applied Chemistry, Faculty of Science and Technology, Keio University

• KONISHIIKE Isamu

  Department of Applied Chemistry, Faculty of Science and Technology, Keio University

• MIURA Takashi

  Department of Applied Chemistry, Faculty of Science and Technology, Keio University

• KISHI Tomiya

  Department of Applied Chemistry, Faculty of Science and Technology, Keio University

Abstract

Electrochemical behavior of trivalent vanadium species was investigated in a Lewis basic 1-ethyl-3-methylimidazolium chloride (EMIC)-aluminum trichloride (AlCl₃) molten salt at room temperature. The reduction of V(III) was observed around −1.2 V vs. Al(III)/Al in the cyclic voltammogram on platinum electrode. The reduction process of V(III) seems electrochemically irreversible as observed in aqueous solution.

Journal

• Electrochemistry

  Electrochemistry 67 (6), 547-549, 1999-06-05

  The Electrochemical Society of Japan

Keywords

• 1-ethyl-3-methylimidazolium Chloride-Aluminum Trichloride
• Vanadium Trichloride

Details

• CRID: 1390564227346889472
• NII Article ID: 10002567386
• NII Book ID: AN00151637
• DOI: 10.5796/electrochemistry.67.547
• ISSN: 21862451
• ISSN: 13443542
• NDL BIB ID: 4740651
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I4740651
• Web Site: https://www.jstage.jst.go.jp/article/electrochemistry/67/6/67_547/_pdf
• Text Lang: en
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• Abstract License Flag: Allowed