A Solubility Study of Prelithiated NiO and Prelithiated Cobaltite as Cathode Materials for MCFC in 62 Li-38 K Eutectic Carbonate Melts
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- ZHANG Xinge
- MCFC division, Ansaldo Ricerche Present address: Japan Fine Ceramics Center (JFCC)
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- CAPOBIANCO Paolo
- MCFC division, Ansaldo Ricerche Present address: Japan Fine Ceramics Center (JFCC)
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- TORAZZA Autora
- MCFC division, Ansaldo Ricerche Present address: Japan Fine Ceramics Center (JFCC)
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- PASSALACQUA Biagio
- MCFC division, Ansaldo Ricerche Present address: Japan Fine Ceramics Center (JFCC)
書誌事項
- タイトル別名
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- Solubility Study of Prelithiated NiO and Prelithiated Cobaltite as Cathode Materials for MCFC in 62Li-38K Eutectic Carbonate Melts
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<p>The solubility of prelithiated NiO and prelithiated cobaltite as cathode materials for MCFC in 62 Li-38 K eutectic carbonate melts was studied with immersion test method. It was found that the solubility of either prelithiated NiO or prelithiated cobaltite was affected by its lithium (Li) content. The higher Li content was, the lower solubility could be in the range of 0∼0.25 mole fraction of Li. With the prelithiated NiO at Li content of 0.2 mole fraction, Ni solubility was reduced to 3∼4 × 10−6 mole fraction, which was only one-third of that of the normal NiO cathode in 30% CO2-70% air at 1 atm. It was obtained that the solubility of prelithiated cobaltite and even LiCoO2 were higher than the prelithiated NiO in the low O2 concentration gas. This suggested that even LiCoO2 was not stable in the O2 depleting condition, and more soluble than NiO.</p>
収録刊行物
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- Electrochemistry
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Electrochemistry 67 (6), 603-607, 1999-06-05
公益社団法人 電気化学会
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詳細情報 詳細情報について
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- CRID
- 1390564227346130304
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- NII論文ID
- 10002567542
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- NII書誌ID
- AN00151637
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- ISSN
- 21862451
- 13443542
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- NDL書誌ID
- 4743522
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用可