Complicated and Various Crystal Structures of Metal Sulfides.

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  • 複雑多様な金属硫化物の結晶構造の解明
  • フクザツ タヨウ ナ キンゾク リュウカブツ ノ ケッショウ コウゾウ ノ カ

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Abstract

Many kinds of complicated crystal structures have appeared in the transition metal sulfide system. Simulation by the matrix method could explain the diffuse scattering observed in nonstoichiometric titanium sulfides with stacking faults, in Ti1.42S2 with short-range order of Ti vacancies, and in some channel-type composite crystals such as Ba0.7Cr2S3.7 with two-directional disorder of positions of filling columns. Crystal structures of incommensurate layered composite crystal (PbS) 1.12VS2, columnar composite crystals Ba10/9Fe2S4 and Ba9/8Fe2S4, and incommensurate columnar composite crystals SrxTiS3 (x=1.1-1.2) were successfully analyzed based on the superspace group approach.

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