水素結合における構造物性と機能　　水素結合の競合とＩｃｅ　Ｒｕｌｅの役割

• 松下 栄子

  岐阜大学工学部

書誌事項

タイトル別名

• Stoructural science and various functions in hydorogen-bond materials. Role of Ice Rule and Competition among Hydrogen Bonds.
• スイソ ケツゴウ ノ キョウゴウ ト Ice Rule ノ ヤクワリ

抄録

In view of the importance of the ice rule imposed on the proton configurations in hydrogen-bonded crystals, a cluster theory is developed and applied to the phase transitions in the mixed crystals of ferroelectrics and antiferroelectrics Rb_1-x (NH₄) _xH₂PO₄. At low temperatures, protons rearrange themselves to fulfill the ice rule condition, and produce the glass structure resulting from the competition between two kinds of proton ordering. It is shown that the correlation among hydrogen bonds under the ice rule constraint leads the system to the new ordered state.

収録刊行物

• 日本結晶学会誌

  日本結晶学会誌 40 (1), 19-25, 1998

  日本結晶学会

詳細情報

• CRID: 1390001204087365632
• NII論文ID: 10002590170
• NII書誌ID: AN00188364
• DOI: 10.5940/jcrsj.40.19
• ISSN: 18845576
• ISSN: 03694585
• NDL書誌ID: 4446280
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I4446280
• 本文言語コード: ja
• データソース種別:
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• 抄録ライセンスフラグ: 使用不可