Stoructural science and various functions in hydorogen-bond materials. The Role of Intermolecular Hydrogen Bond in Solid State Photoisomerization.

• OHASHI Yuji

  東京工業大学理学部化学科

• SEKINE Akiko

  東京工業大学理学部化学科

Bibliographic Information

Other Title

• 水素結合における構造物性と機能　　固相光異性化反応における分子間水素結合の役割
• コソウ ヒカリ イセイカ ハンノウ ニ オケル ブンシカン スイソ ケツゴウ

Abstract

The hydrogen bond plays important roles in the reactions of molecular crystals. If the reactive group of the molecule is hydrogen bonded with the neighboring molecules in the crystal, the hydrogen bond severely influences the reactivity of the molecule, because it (1) changes the electronic state of the reactive group and/or (2) inhibits the migration of the group in the process of reaction. Even if the hydrogen bond has no connection with the reactive group, it strengthens the crystal lattice and accelerates the photoreactions since not only the energy to destroy the crystalline lattice is unnecessary but also light can easily penetrate into the crystal. The hydrogen migration in the solid-state reactions can be directly observed by neutron diffraction when only the peculiar hydrogen atom considered can be replaced with the deuterium atom.

Journal

• Nihon Kessho Gakkaishi

  Nihon Kessho Gakkaishi 40 (1), 90-94, 1998

  The Crystallographic Society of Japan

Details

• CRID: 1390001204087380736
• NII Article ID: 10002590401
• NII Book ID: AN00188364
• DOI: 10.5940/jcrsj.40.90
• ISSN: 18845576
• ISSN: 03694585
• NDL BIB ID: 4446293
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I4446293
• Text Lang: ja
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• Abstract License Flag: Disallowed