水のラマン散乱と水素結合によるクラスター [in Japanese] Raman Scattering of Liquid Water and Hydrogen-Bonded Cluster [in Japanese]
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Depolarized low-frequency Raman spectra below 250 cm<SUP>-1</SUP> in liquid water have been well interpreted by a decomposition of one Cole-Cole type relaxation mode and two intermolecular vibration modes of tetrahedrally coordinated structure due to hydrogen bonds. High-frequency Raman spectra between 300 cm<SUP>-1</SUP> and 4000 cm<SUP>-1</SUP> in liquid water have been well explained by a molecular vibration pattern of temporal C<SUB>2v</SUB> distorted tetrahedral-like structure around oxygen atom. This new interpretation is alternative to a conventional one.
X-RAYS 40(1), 95-100, 1998-02-28
The Crystallographic Society of Japan