ヘリウムを圧力媒体とした高圧単結晶構造解析 [in Japanese] Single Crystal Structure Analysis under High Pressures Using Helium as a Pressure Transmitting Medium [in Japanese]
Access this Article
Search this Article
In this paper, a technique of single-crystal X-ray diffraction measurements under high pressures, using a diamond anvil cell with helium gas as an inert and hydrostatic pressuretransmitting medium, is described. The technique has been applied to a three-dimensional halogen-bridged mixed-valence gold complex, CS<SUB>2</SUB> [Au<SUP>I</SUP>Cl<SUB>2</SUB>] [Au<SUP>III</SUP>Cl<SUB>4</SUB>] to investigate the mixedvalence state and the crystal structure under high pressures up to 18 GPa.
X-RAYS 41(1), 17-24, 1999-02-28
The Crystallographic Society of Japan