X-ray Structure Determination of Endohedral Metallofullerenes.

• TAKATA Masaki

  Department of Material Science, Shimane University

Bibliographic Information

Other Title

• Ｘ線回折法による金属内包フラーレンの構造研究
• Xセン カイセツホウ ニ ヨル キンゾク ナイホウ フラーレン ノ コウゾウ ケンキュウ

Abstract

Endohedral metallofullerenes are novel forms of fullerene-related materials, which encage metal atom inside a carbon cage. The recent X-ray structural studies of metallofullerenes, Sc@C₈₂ and Sc₂@C₈₄, by the synchrotron powder diffraction experiment are presented to illustrate the usefulness of the MEM/Rietveld analysis, which is a self-consistent iterative way in combination with the MEM (Maximum Entropy Method) and Rietveld analyses. The obtained MEM charge densities clearly reveal the distinct features of encapsulated metals inside the fullerene cages as well as endohedral cage structures for Sc@C₈₂ and Sc₂@C₈₄.

Journal

• Nihon Kessho Gakkaishi

  Nihon Kessho Gakkaishi 41 (2), 112-121, 1999

  The Crystallographic Society of Japan

Details

• CRID: 1390001204085767296
• NII Article ID: 10002591571
• NII Book ID: AN00188364
• DOI: 10.5940/jcrsj.41.112
• DOI: 10.5940/jcrsj.40.supplement_3
• COI: 1:CAS:528:DyaK1MXjtlKrsbk%3D
• ISSN: 18845576
• ISSN: 03694585
• NDL BIB ID: 4732008
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I4732008
• Text Lang: ja
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• Abstract License Flag: Disallowed