Complexation Kinetics of 5-Octyloxymethyl-8-quinolinol with Ni(II)at the Heptane-Water Interface

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著者

    • SHIOYA Takeshi
    • Department of Chemistry, Graduate School of Science, Tohoku University
    • TERAMAE Norio
    • Department of Chemistry, Graduate School of Science, Tohoku University

抄録

Complexation kinetics of 5-octyloxymethyl-8-quinolinol (Hocqn) with Ni(II) at the heptane-water interface was studied by measuring the dynamic interfacial tension. Decrease in the interfacial tension was caused by the adsorption of 1:1 complex formed at the interface. It was found that the complexation rate at the interface was 43 times faster than that in the bulk, and that the rate also depended on the counter-anion in the aqueous phase.

収録刊行物

  • Chemistry letters  

    Chemistry letters 1996(6), 469-470, 1996-06 

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10002604009
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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