syn-trans Fused Bicyclic Ether Formation via Acetylene-biscobalthexacarbonyl Complex

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著者

    • ISOBE Minoru
    • Laboratory of Organic Chemistry, School of Agricultural Science, Nagoya University
    • HOSOKAWA Seijiro
    • Laboratory of Organic Chemistry, School of Agricultural Science, Nagoya University
    • KIRA Kazunobu
    • Laboratory of Organic Chemistry, School of Agricultural Science, Nagoya University

抄録

Medium size bicyclic ethers of 7-, 8-, and 9-membered rings were synthesized by connection between a hydroxy group on dihydropyranyl ring and a propargylic cation that was stabilized as an acetylene biscobalthexacarbonyl complex under acidic conditions. This cyclization selectively afforded the <I>syn</I>-<I>trans</I> bicyclic ring system often seen in marine toxins such as ciguatoxin.

収録刊行物

  • Chemistry letters

    Chemistry letters 1996(6), 473-474, 1996-06

    The Chemical Society of Japan

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被引用文献:  1件中 1-1件 を表示

各種コード

  • NII論文ID(NAID)
    10002604040
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  CJP引用  J-STAGE 
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