Reaction and Stereochemistry of C-Glycosidation in 2-Deoxy-4-Thioribofuranoside [in Japanese]
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SnCl<SUB>4</SUB> mediated C-glycosidation reactions of ethyl 2-deoxy-4-thioribofuranoside with silylated nucleophiles were described. α-Anomer was the major product formed in the reactions. The stereochemical course was found to be similar to that of ethyl 2-deoxyribofuranoside.
- Chemistry Letters
Chemistry Letters 1996(8), 595-596, 1996-08
The Chemical Society of Japan