Photochemistry of π-Complexes of Chlorine Atom with Methyl- and Ethyl-Substituted Benzenes

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著者

    • FENG Wu
    • Department of Atomic Science and Nuclear Engineering, Faculty of Engineering, Hokkaido University
    • SUMIYOSHI Takashi
    • Department of Atomic Science and Nuclear Engineering, Faculty of Engineering, Hokkaido University
    • YAMASHITA Yuichiro
    • Department of Atomic Science and Nuclear Engineering, Faculty of Engineering, Hokkaido University
    • SHINDO Toshihiko
    • Department of Atomic Science and Nuclear Engineering, Faculty of Engineering, Hokkaido University
    • SAWAMURA Sadashi
    • Department of Atomic Science and Nuclear Engineering, Faculty of Engineering, Hokkaido University

抄録

The photochemistry of π-complexes of the chlorine atom with a series of methyl- and ethyl-substituted benzenes has been investigated using combined pulse radiolysis-laser flash photolysis techniques. Direct photolysis of π-complexes in carbon tetrachloride causes photobleaching by intramolecular hydrogen abstraction with quantum yields of 0.05–0.15 depending on the substituents but not on the positions of them.

収録刊行物

  • Chemistry letters

    Chemistry letters 1996(8), 643-644, 1996-08

    公益社団法人 日本化学会

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各種コード

  • NII論文ID(NAID)
    10002605123
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    JPN
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  CJP引用  J-STAGE 
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