Photochemistry of π-Complexes of Chlorine Atom with Methyl- and Ethyl-Substituted Benzenes
The photochemistry of π-complexes of the chlorine atom with a series of methyl- and ethyl-substituted benzenes has been investigated using combined pulse radiolysis-laser flash photolysis techniques. Direct photolysis of π-complexes in carbon tetrachloride causes photobleaching by intramolecular hydrogen abstraction with quantum yields of 0.05–0.15 depending on the substituents but not on the positions of them.
- Chemistry letters
Chemistry letters 1996(8), 643-644, 1996-08