Solvent-Dependent cis-trans One-Way Photoisomerization of Bisformyl-Substituted 1,6-Diphenyl-1, 3, 5-hexatriene

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抄録

<I>trans,trans,trans</I>-1,6-Bis(<I>p</I>-formylphenyl)-1,3,5-hexatriene underwent stereoselective photoisomerization to give its <I>cis,trans,trans</I> isomer regardless of the solvent polarity. Quantum yields of <I>trans,trans,trans</I>-to-<I>cis,trans,trans</I> isomerization decreased dramatically with decreasing solvent polarity, whereas those of the reverse reaction gradually increased. This led to the <I>cis,trans,trans</I>-to-<I>trans,trans,trans</I> 'one-way' isomerization in nonpolar solvents.

収録刊行物

  • Chemistry letters

    Chemistry letters 1996(8), 659-660, 1996-08

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10002605237
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    JPN
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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