Solvent-Dependent <i>cis-trans</i> One-Way Photoisomerization of Bisformyl-Substituted 1,6-Diphenyl-1,3,5-hexatriene

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<jats:title>Abstract</jats:title> <jats:p>trans,trans,trans-1,6-Bis(p-formylphenyl)-1,3,5-hexatriene underwent stereoselective photoisomerization to give its cis,trans,trans isomer regardless of the solvent polarity. Quantum yields of trans,trans,trans-to-cis,trans,trans isomerization decreased dramatically with decreasing solvent polarity, whereas those of the reverse reaction gradually increased. This led to the cis,trans,trans-to-trans,trans,trans ‘one-way’ isomerization in nonpolar solvents.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 25 (8), 659-660, 1996-08-01

    Oxford University Press (OUP)

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