Some Mechanistic Evidence for an Oxygen Transfer Reaction Accompanied by the Redox-Induced Nitrito-Nitro Linkage Isomerization of Ruthenium Complex Having Nitrosyl, cis-[Ru(NO)(X)(bpy)_2]^<2+>(X=ONO, NO_2)

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著者

    • OOYAMA Dai
    • Department of Chemistry, Faculty of Science and Engineering, Sophia University
    • NAGAO Hirotaka
    • Department of Chemistry, Faculty of Science and Engineering, Sophia University
    • NAGAO Noriharu
    • Department of Chemistry, Faculty of Science and Engineering, Sophia University
    • HOWELL F. Scott
    • Department of Chemistry, Faculty of Science and Engineering, Sophia University
    • MUKAIDA Masao
    • Department of Chemistry, Faculty of Science and Engineering, Sophia University

抄録

An oxygen transfer between the NO and the ONO ligands occurs in <I>cis</I>-[Ru(NO)(ONO)(bpy)<SUB>2</SUB>]<SUP>2+</SUP> when the complex undergoes a redox-induced nitrito-to-nitro linkage isomerization. Such an oxygen transfer does not occur in a themally-induced linkage isomerization reported previously.

収録刊行物

  • Chemistry letters  

    Chemistry letters 1996(9), 759-760, 1996-09 

    The Chemical Society of Japan

参考文献:  15件

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各種コード

  • NII論文ID(NAID)
    10002605964
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    JPN
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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