Far-Wing Excitation Spectra of the Hg 6s6p 3<i>P</i>0 – 6s7s 3<i>S</i>1 Inter-Excited-State Transitions Broadened by Ar and Ne

  • Kenji Ohmori
    Research Institute for Scientific Measurements, Tohoku University
  • Kazuhiro Amano
    Research Institute for Scientific Measurements, Tohoku University
  • Misaki Okunishi
    Research Institute for Scientific Measurements, Tohoku University
  • Hisashi Chiba
    Research Institute for Scientific Measurements, Tohoku University
  • Kiyoshi Ueda
    Research Institute for Scientific Measurements, Tohoku University
  • Yukinori Sato
    Research Institute for Scientific Measurements, Tohoku University

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Abstract

<jats:title>Abstract</jats:title> <jats:p>We have measured the laser-excitation spectra of the Hg–Ar and Hg–Ne collisional quasimolecules in the far wings of the Hg 6s6p 3P0 – 6s7s 3S1 inter-excited-state transitions broadened by Ar and Ne. The simulation of the spectrum, based on an uniform-semiclassical treatment for the free-free Franck-Condon factor, has been carried out for the Hg–Ar system in order to estimate the potential curves for the E31 and a  30− states of the quasimolecule.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 25 (9), 765-766, 1996-09-01

    Oxford University Press (OUP)

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