Tetrabutylammonium Fluoride Promoted Regiospecific Reactions of Trimethylsilyl-o-Carborane with Aldehydes [in Japanese]
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Trimethylsilyl-<I>o</I>-carborane serves as <I>o</I>-carborane carbanion upon fluoride ion promoted reaction with carbonyl compounds. Thus, in the presence of tetrabutylammonium fluoride, trimethylsilyl-<I>o</I>-carborane undergoes facile, unprecedented, carbodesilylation with aromatic and aliphatic aldehydes.
- Chemistry Letters
Chemistry Letters 1996(9), 791-792, 1996-09
The Chemical Society of Japan