ESR Studies on Poly(methyl acrylate)Radicals to Estimate Their Dominant Structure

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著者

    • SUGIYAMA Yoshio
    • Advanced Technology Research Laboratories, Nippon Steel Corporation

抄録

Electron Spin Resonance (ESR) examinations of the propagating radicals in the polymerization of methyl acrylate (MA) and methyl acrylate-α-d (MA-d) in the frozen state have been made. Selective deuteration of MA showed that the propagating radicals have the chain-end (I) and not the mid-chain (II) structure. The stable conformation of poly (methyl acrylate) (poly (MA)) radical was also determined.

収録刊行物

  • Chemistry letters

    Chemistry letters 1996(11), 951-952, 1996-11

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10002607322
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    JPN
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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