Investigation on the Electron-transfer Interaction of the Two Ferrocene Moieties Bridged by Ni2+ or Cu2+ and Its Mixed-valence Complexes

  • Zhi Yu
    Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Center for Advanced Studies in Science and Technology, of Microstructures, Nanjing University
  • Yuan Zhou
    Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Center for Advanced Studies in Science and Technology, of Microstructures, Nanjing University
  • Wei Yang
    Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Center for Advanced Studies in Science and Technology, of Microstructures, Nanjing University
  • Yunpeng Tian
    Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Center for Advanced Studies in Science and Technology, of Microstructures, Nanjing University
  • Cun-ying Duan
    Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Center for Advanced Studies in Science and Technology, of Microstructures, Nanjing University
  • Rongchuan Liu
    Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Center for Advanced Studies in Science and Technology, of Microstructures, Nanjing University
  • Xiaozeng You
    Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Center for Advanced Studies in Science and Technology, of Microstructures, Nanjing University

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<jats:title>Abstract</jats:title> <jats:p>Investigation of the new mixed-valence trinuclear complexes of FcMFc (M = Ni, Cu) indicates that intramolecular long-range charge transfer for FcNiFc complex processes in timescale 1.6•106 s−1 through a long bridge including a coordinated bond at room temperature.</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 25 (11), 957-958, 1996-11-01

    Oxford University Press (OUP)

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