Novel Aggregation of fac(S)-[Rh(aet)_3]by Square-Planar Palladium(II) : Crystal Structure of Spontaneously Resolved Rh^<III>_3Pd^<II>_2 Pentanuclear Complex [Pd{Pd(aet)}{Rh(aet)_2}{Rh(aet)_3}_2]Br_4(aet=2-Aminoethanethiolate)

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The reaction of <I>fac(S)</I>-[Rh(aet)<SUB>3</SUB>] (aet = NH<SUB>2</SUB>CH<SUB>2</SUB>CH<SUB>2</SUB>S<SUP>−</SUP>) with Pd<SUP>II</SUP> gave a novel S-bridged Rh<SUP>III</SUP><SUB>3</SUB>Pd<SUP>II</SUP><SUB>2</SUB> pentanuclear complex, [Pd{Pd(aet)}{Rh(aet)<SUB>2</SUB>}{Rh(aet)<SUB>3</SUB>}<SUB>2</SUB>]<SUP>4+</SUP> (<B>1</B>), of which bromide salt was spontaneously resolved. <B>1</B> was converted into [Pd{Pd(aet)}{Rh(aet)(NH<SUB>2</SUB>CH<SUB>2</SUB>CH<SUB>2</SUB>SCH<SUB>3</SUB>)}{Rh(aet)<SUB>3</SUB>}<SUB>2</SUB>]<SUP>5+</SUP> (<B>2</B>) by methylation reaction.

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  • Chemistry letters  

    Chemistry letters 1996(11), 977-978, 1996-11 

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10002607494
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    JPN
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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