Novel Aggregation of <i>fac(S)</i>-[Rh(aet)3] by Square-Planar Palladium(II): Crystal Structure of Spontaneously Resolved RhIII3PdII2 Pentanuclear Complex [Pd{Pd(aet)}{Rh(aet)2}{Rh(aet)3}2]Br4 (aet = 2-Aminoethanethiolate)

• Takumi Konno

  Department of Chemistry, University of Tsukuba

• Chieko Sasaki

  Department of Chemistry, University of Tsukuba

• Ken-ichi Okamoto

  Department of Chemistry, University of Tsukuba

Abstract

The reaction of fac(S)-[Rh(aet)3] (aet = NH2CH2CH2S−) with PdII gave a novel S-bridged RhIII3PdII2 pentanuclear complex, [Pd{Pd(aet)}{Rh(aet)2}{Rh(aet)3}2]4+ (1), of which bromide salt was spontaneously resolved. 1 was converted into [Pd{Pd(aet)}{Rh(aet)(NH2CH2CH2SCH3)}{Rh(aet)3}2]5+ (2) by methylation reaction.

Journal

• Chemistry Letters

  Chemistry Letters 25 (11), 977-978, 1996-11-01

  Oxford University Press (OUP)

Keywords

• General Chemistry

Details

• CRID: 1360283694085979776
• NII Article ID: 10002607494
• NII Book ID: AA00603318
• DOI: 10.1246/cl.1996.977
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/25/11/977/56071072/cl.1996.977.pdf
• Data Source:
  • Crossref
  • CiNii Articles