Electrochemical Syntheses and Electrochromic Properties of Chromium Cyanide Magnetic Thin Films
Electrochemical preparation method and electromic properties of the mixed valence chromium cyanide thin film, which is one of the ferrimagnet with highest critical temparature (T<SUB>c</SUB>) among molecule-based magnets, were described. The difference in the ability of the ligand substitution reaction between Cr<SUP>II</SUP> and Cr<SUP>III</SUP> was utilized to synthesize the prussian blue analogs. The obtained magnetic material exhibited an excellent electrochromic properties. This indicates the compound has a potential for future display devices, as well as tunable molecule-based magnetic devices.
- Chemistry letters
Chemistry letters 1997(1), 37-38, 1997-01
The Chemical Society of Japan