Enantioselective Allylation of Aldehydes Using Tartrate Eastr Modified Allylsilanes

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著者

    • ZHANG Luo Cheng
    • Department of Chemistry, Graduate School of Science, Tohoku University
    • SAKURAI Hideki
    • Department of Chemistry, Graduate School of Science, Tohoku University
    • KIRA Mitsuo
    • Department of Chemistry, Graduate School of Science, Tohoku University

抄録

Tartrate-ester modified allylsilanes, 2-allyl-1,3,2-dioxasilolane-4,5-dicarboxylic esters, (<B>1</B>), were found to serve as useful reagents for regiospecific and stereoselecive allylation of aldehydes. Reactions of <B>1</B> with achiral aldehydes without any catalyst gave the corresponding homoallyl alcohols in good yields (70-90%) with the ee values up to 80%.

収録刊行物

  • Chemistry letters  

    Chemistry letters 1997(2), 129-130, 1997-02 

    The Chemical Society of Japan

参考文献:  18件

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各種コード

  • NII論文ID(NAID)
    10002609626
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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