Intermolecular <i>π</i>-<i>π</i> Interaction of Poly(4,4′-dialkyl-2,2′-bithiazole-5,5′-diyl)s and Photoluminescence of the Polymers

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  • Takakazu Yamamoto
    Research Laboratory of Resources Utilization, Tokyo Institute of Technology4259 Nagatsuta, Midori-ku, Yokohama
  • Tsukasa Maruyama
    Research Laboratory of Resources Utilization, Tokyo Institute of Technology4259 Nagatsuta, Midori-ku, Yokohama
  • Hajime Suganuma
    Research Laboratory of Resources Utilization, Tokyo Institute of Technology4259 Nagatsuta, Midori-ku, Yokohama
  • Minoru Arai
    Research Laboratory of Resources Utilization, Tokyo Institute of Technology4259 Nagatsuta, Midori-ku, Yokohama
  • Dharma Komarudin
    Research Laboratory of Resources Utilization, Tokyo Institute of Technology4259 Nagatsuta, Midori-ku, Yokohama
  • Shintaro Sasaki
    Japan Advanced Institute of Science and Technology1-1 Asahidai, Tatsunokuchi, Ishikawa

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<jats:title>Abstract</jats:title> <jats:p>UV-vis. adsorption spectra of films of regioregular poly(4,4′-dialkyl-2,2′-bithiazole-5,5′-diyl)s PRBTz’s show bathochromic shifts from those of PRBTz’s in solutions and their corresponding regio-irregular polymers. This bathchromic shift is considered to originate from stacking of the polymer, and powder X-ray diffraction and photoluminescence data support this view.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 26 (2), 139-140, 1997-02-01

    Oxford University Press (OUP)

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