A Carbene•Phosphinidene Adduct: “Phosphaalkene”

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  • Anthony J Arduengo
    DuPont Science and Engineering LaboratoryExperimental Station, Wilmington, Delaware 19880-0328, U.S.A
  • H V Rasika Dias
    DuPont Science and Engineering LaboratoryExperimental Station, Wilmington, Delaware 19880-0328, U.S.A
  • Joseph C Calabrese
    DuPont Science and Engineering LaboratoryExperimental Station, Wilmington, Delaware 19880-0328, U.S.A

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<jats:title>Abstract</jats:title> <jats:p>The synthesis, characterization and X-ray crystallographic structure determination are described for a “phosphaalkene” formally derived from 1,3,4,5-tetramethylimidazol-2-ylidene and phenylphosphinidene. This carbene•phosphinidene adduct has a central P-C bond length of 179.4 pm and a dihedral twist of 46° which indicates a very weak C-P pπ-pπ interaction. The valence angle at phosphorus in 102.3°.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 26 (2), 143-144, 1997-02-01

    Oxford University Press (OUP)

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