Synthesis and Reactivity of S-Sulfiliminothiazynes

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著者

    • OHKUBO Masanori
    • Department of Chemical and Biochemical Engineering, Faculty of Engineering, Toyama University
    • FUJII Takayoshi
    • Department of Chemical and Biochemical Engineering, Faculty of Engineering, Toyama University
    • ONO Shin
    • Department of Chemical and Biochemical Engineering, Faculty of Engineering, Toyama University
    • MORITA Hiroyuki
    • Department of Chemical and Biochemical Engineering, Faculty of Engineering, Toyama University
    • YOSHIMURA Toshiaki
    • Department of Chemical and Biochemical Engineering, Faculty of Engineering, Toyama University
    • HORN Ernst
    • Tsukuba Advanced Research Alliance Center, Department of Chemistry, University of Tsukuba
    • SATO Soichi
    • Tsukuba Advanced Research Alliance Center, Department of Chemistry, University of Tsukuba

抄録

Reaction of <I>S</I>,<I>S</I>-diphenyl-<I>S</I>-fluorothiazyne with <I>N</I>-unsubstituted <I>S</I>,<I>S</I>-diphenylsulfilimine afforded the corresponding <I>S</I>-sulfiliminothiazyne. Measurement of the pKa value of <I>S</I>-sulfiliminothiazyne and its reactivity were examined. The molecular structure of the sulfonediiminosulfonium salt was determined by the X-ray crystallographic analysis.

収録刊行物

  • Chemistry letters

    Chemistry letters 1997(2), 153-154, 1997-02

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10002609803
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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