Synthesis and Reactivity of S-Sulfiliminothiazynes
Access this Article
Search this Article
Reaction of <I>S</I>,<I>S</I>-diphenyl-<I>S</I>-fluorothiazyne with <I>N</I>-unsubstituted <I>S</I>,<I>S</I>-diphenylsulfilimine afforded the corresponding <I>S</I>-sulfiliminothiazyne. Measurement of the pKa value of <I>S</I>-sulfiliminothiazyne and its reactivity were examined. The molecular structure of the sulfonediiminosulfonium salt was determined by the X-ray crystallographic analysis.
- Chemistry Letters
Chemistry Letters 1997(2), 153-154, 1997-02
The Chemical Society of Japan