Alcoholysis of Benzotrichloride Studied by Liquid Beam - Multiphoton Ionization Technique

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著者

    • HORIMOTO Noriko
    • Department of Chemistry, School of Science, The University of Tokyo
    • MAFUNE Fumitaka
    • Department of Chemistry, School of Science, The University of Tokyo
    • KONDOW Tamotsu
    • Department of Chemistry, School of Science, The University of Tokyo

抄録

Chemical reactions of benzotrichloride in an alcohol solution initiated by multiphoton ionization were observed by irradiation of a tightly focused laser beam at wavelength of 274 nm. The product ions ejected from the liquid surface were analyzed by a time-of-flight mass spectrometer. The mass spectra of the ions indicate that alcoholysis occurs between PhCCl<SUB>2</SUB><SUP>+</SUP> produced by multiphoton ionization and alcohol molecules, ROH, giving PhCCl(OR)<SUP>+</SUP> and PhC(OR)<SUB>2</SUB><SUP>+</SUP>.

収録刊行物

  • Chemistry letters

    Chemistry letters 1997(2), 159-160, 1997-02

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10002609830
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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