Cleavage Mode of Benzyltributylstannane Radical Cations Produced in Photoinduced Electron Transfer

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著者

    • YASUI Kiyomi
    • Department of Applied Chemistry, Faculty of Engineering, Osaka University
    • ITOH Shinobu
    • Department of Applied Chemistry, Faculty of Engineering, Osaka University

抄録

Cleavage of metal-carbon bond of benzyltributylstannane radical cation produced in photoinduced electron transfer from benzyltributylstannane to 10-methylacridinium ion occurs to give benzyl radical rather than benzyl cation, resulting in formation of 9-benzyl-10-methyl-9,10-dihydroacridine selectively in dehydrated acetonitrile. In the presence of water, however, 10-methyl-9,10-dihydroacridine is also formed via electron transfer from benzyl radical to the dihydroacridine radical cation produced by protonation of acridinyl radical following the initial photoinduced electron transfer.

収録刊行物

  • Chemistry letters

    Chemistry letters 1997(2), 161-162, 1997-02

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10002609843
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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