Cleavage Mode of Benzyltributylstannane Radical Cations Produced in Photoinduced Electron Transfer
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- Shunichi Fukuzumi
- Department of Applied Chemistry, Faculty of Engineering, Osaka UniversityYamadaoka, Suita, Osaka
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- Kiyomi Yasui
- Department of Applied Chemistry, Faculty of Engineering, Osaka UniversityYamadaoka, Suita, Osaka
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- Shinobu Itoh
- Department of Applied Chemistry, Faculty of Engineering, Osaka UniversityYamadaoka, Suita, Osaka
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<jats:title>Abstract</jats:title> <jats:p>Cleavage of metal-carbon bond of benzyltributylstannane radical cation produced in photoinduced electron transfer from benzyltributylstannane to 10-methylacridinium ion occurs to give benzyl radical rather than benzyl cation, resulting in formation of 9-benzyl-10-methyl-9,10-dihydroacridine selectively in dehydrated acetonitrile. In the presence of water, however, 10-methyl-9,10-dihydroacridine is also formed via electron transfer from benzyl radical to the dihydroacridine radical cation produced by protonation of acridinyl radical following the initial photoinduced electron transfer.</jats:p>
収録刊行物
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- Chemistry Letters
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Chemistry Letters 26 (2), 161-162, 1997-02-01
Oxford University Press (OUP)
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詳細情報
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- CRID
- 1360002219109315712
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- NII論文ID
- 10002609843
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- NII書誌ID
- AA00603318
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- ISSN
- 13480715
- 03667022
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