Generation of α-Alkylthio Radicals by Photoinduced One-Electron Oxidation of α-Stannyl Sulfides and Their Use for Carbon-Carbon Bond Formation
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Cation radicals, generated from <I>α</I>-stannyl sulfides by the photoinduced single electron transfer, cleave into <I>α</I>-alkylthio radical intermediates with the elimination of the stannyl group. The <I>α</I>-alkylthio radicals thus formed are utilized for carbon-carbon bond forming reactions.
- Chemistry Letters
Chemistry Letters 1997(2), 169-170, 1997-02
The Chemical Society of Japan