Generation of <i>α</i>-Alkylthio Radicals by Photoinduced One-Electron Oxidation of <i>α</i>-Stannyl Sulfides and Their Use for Carbon-Carbon Bond Formation

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  • Generation of α-Alkylthio Radicals by Photoinduced One-Electron Oxidation of α-Stannyl Sulfides and Their Use for Carbon-Carbon Bond Formation

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Cation radicals, generated from α-stannyl sulfides by the photoinduced single electron transfer, cleave into α-alkylthio radical intermediates with the elimination of the stannyl group. The α-alkylthio radicals thus formed are utilized for carbon-carbon bond forming reactions.

収録刊行物

  • Chemistry Letters

    Chemistry Letters 26 (2), 169-170, 1997

    Chemical Society of Japan

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