Photochemical Behavior of Indane-1, 2, 3-trione in Degassed Alcoholic Solutions : Formation of 3-Substituted Phthalides

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著者

    • TATSUGI Jiro
    • Department of Applied Chemistry, Aichi Institute of Technology
    • HARA Tomoaki
    • Department of Applied Chemistry, Aichi Institute of Technology
    • IZAWA Yasuji
    • Department of Applied Chemistry, Aichi Institute of Technology

抄録

Irradiation of indane-1,2,3-trione in degassed alcoholic solutions affords 3-alkoxycarbonylphthalides as the major product together with 3-alkoxyphthalides. 3-Alkoxycarbonylphthalides may be derived from the reaction between alcohols and the spirooxiranone intermediate, generated photochemically by cleavage of the bond between two carbonyl groups of indane-1,2,3-trione <I>via</I> a cyclobutenone biradical derivative.

収録刊行物

  • Chemistry letters

    Chemistry letters 1997(2), 177-178, 1997-02

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10002609948
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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