Linear Trinuclear Copper(II) Complexes Bridged by Oximato and Azido or Hydroxo Groups

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著者

    • AKAGI Fumio
    • Chemical Laboratory, Faculty of Education, Okayama University
    • NAKAO Yasuo
    • Chemical Laboratory, Faculty of Education, Okayama University
    • MORI Wasuke
    • Department of Chemistry, Faculty of Science, Kanagawa University

抄録

The linear trinuclear copper(II) complexes Cu<SUB>3</SUB>(L<SUB>1</SUB>)<SUB>2</SUB>(N<SUB>3</SUB>)<SUB>2</SUB>(NO<SUB>3</SUB>)<SUB>2</SUB>·2H<SUB>2</SUB>O·2CH<SUB>3</SUB>OH <B>1</B> and Cu<SUB>3</SUB>(L<SUB>1</SUB>)<SUB>2</SUB>(OH)<SUB>2</SUB>(ClO<SUB>4</SUB>)<SUB>2</SUB> <B>2</B> containing 3-[{2-(2-pyridinyl)ethyl}imino]-2-butanone oximato ligand (L<SUB>1</SUB>) were prepared; the crystal structure of <B>1</B> was determined by X-ray crystallography. Magnetic susceptibility measurements from liquid helium temperature to room temperature showed a vary strong antiferromagnetic exchange coupling between copper(II) ions(<I>J</I> = −266 cm<SUP>−1</SUP> and −245 cm<SUP>−1</SUP> for <B>1</B> and <B>2</B>, respectively, <I>H</I>=−2<I>JS</I><SUB>1</SUB>·<I>S</I><SUB>2</SUB>).

収録刊行物

  • Chemistry letters

    Chemistry letters 1997(2), 181-182, 1997-02

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10002609970
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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