Unexpected Ligand Displacement of Ru(cod)(cot)with Trimethylphosphine to Give fac-Ru(6-η^3 : 1-3-η^3-C_8H_<10>)(PMe_3)_3

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著者

    • HIRANO Masafumi
    • Department of Applied Chemistry, Faculty of Technology, Tokyo University of Agriculture and Technology
    • MARUMO Tsuyoshi
    • Department of Applied Chemistry, Faculty of Technology, Tokyo University of Agriculture and Technology
    • MIYASAKA Takashi
    • Department of Applied Chemistry, Faculty of Technology, Tokyo University of Agriculture and Technology
    • FUKUOKA Atsushi
    • Department of Applied Chemistry, Faculty of Technology, Tokyo University of Agriculture and Technology
    • KOMIYA Sanshiro
    • Department of Applied Chemistry, Faculty of Technology, Tokyo University of Agriculture and Technology

抄録

Selective ligand displacement of the cod ligand in Ru(cod)(cot) (<B>1</B>) [cod: 1,5-cyclooctadiene, cot: 1,3,5-cyclooctatriene] with trimethylphosphine gives <I>fac</I>-Ru(6-<I>η</I><SUP>1</SUP>:1-3-<I>η</I><SUP>3</SUP>-C<SUB>8</SUB>H<SUB>10</SUB>)(PMe<SUB>3</SUB>)<SUB>3</SUB> (<B>3</B>) in benzene at 50 °C.

収録刊行物

  • Chemistry letters

    Chemistry letters 1997(4), 297-298, 1997-04

    公益社団法人 日本化学会

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各種コード

  • NII論文ID(NAID)
    10002610728
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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