Unexpected Ligand Displacement of Ru(cod)(cot) with Trimethylphosphine to Give <i>fac</i>-Ru(6-<i>η</i>1:1-3-<i>η</i>3-C8H10)(PMe3)3

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  • Masafumi Hirano
    Department of Applied Chemistry, Faculty of Technology, Tokyo University of Agriculture and Technology2-24-16 Nakacho, Koganei, Tokyo
  • Tsuyoshi Marumo
    Department of Applied Chemistry, Faculty of Technology, Tokyo University of Agriculture and Technology2-24-16 Nakacho, Koganei, Tokyo
  • Takashi Miyasaka
    Department of Applied Chemistry, Faculty of Technology, Tokyo University of Agriculture and Technology2-24-16 Nakacho, Koganei, Tokyo
  • Atsushi Fukuoka
    Department of Applied Chemistry, Faculty of Technology, Tokyo University of Agriculture and Technology2-24-16 Nakacho, Koganei, Tokyo
  • Sanshiro Komiya
    Department of Applied Chemistry, Faculty of Technology, Tokyo University of Agriculture and Technology2-24-16 Nakacho, Koganei, Tokyo

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Abstract

<jats:title>Abstract</jats:title> <jats:p>Selective ligand displacement of the cod ligand in Ru(cod)(cot) (1) [cod: 1,5-cyclooctadiene, cot: 1,3,5-cyclooctatriene] with trimethylphosphine gives fac-Ru(6-η1:1-3-η3-C8H10)(PMe3)3 (3) in benzene at 50 °C.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 26 (4), 297-298, 1997-04-01

    Oxford University Press (OUP)

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