Regioselective Introduction of 2-Propynyl Groups into the C-2 or C-3 Position of Furanoside Ring

この論文にアクセスする

この論文をさがす

著者

    • KUBOTA Dai
    • Department of Chemistry, College of Science and Engineering, Aoyama Gakuin University
    • OYO Mitsunobu
    • Department of Chemistry, College of Science and Engineering, Aoyama Gakuin University

抄録

The reaction of methyl 2,3-anhydro-α-<FONT SIZE=-2>D</FONT>-ribofuranoside or methyl 2,3-anhydro-5,6-<I>O</I>-cyclohexylidene-α-<FONT SIZE=-2>D</FONT>-allofuranoside with 2-propynyl metallic reagents exclusively gave the corresponding 2-<I>C</I>-(2-propynyl)-<I>arabino</I>-pentofuranosides and 2-<I>C</I>-(2-propynyl)-<I>altro</I>-hexofuranosides, respectively. In contrast, the β-anomers were selectively attacked at the position 3 to afford the corresponding 3-<I>C</I>-(2-propynyl)furanosides.

収録刊行物

  • Chemistry letters  

    Chemistry letters 1997(6), 517-518, 1997-06 

    公益社団法人 日本化学会

参考文献:  9件

参考文献を見るにはログインが必要です。ユーザIDをお持ちでない方は新規登録してください。

各種コード

  • NII論文ID(NAID)
    10002612304
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
ページトップへ