Organoaluminum-Promoted Rearrangement of Epoxysilanes to <i>α</i>-Silylaldehydes
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- Takashi Ooi
- Department of Chemistry, Graduate School of Science, Hokkaido UniversitySapporo
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- Toshitaka Kiba
- Department of Chemistry, Graduate School of Science, Hokkaido UniversitySapporo
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- Keiji Maruoka
- Department of Chemistry, Graduate School of Science, Hokkaido UniversitySapporo
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Abstract
<jats:title>Abstract</jats:title> <jats:p>Selective rearrangement of epoxysilanes to α-silylaldehydes has been achieved with high efficiency by using exceptionally bulky oxygenophilic methylaluminum bis(4-bromo-2,6-di-tert-butylphenoxide) (MABR) as a stoichiometric reagent. Catalytic use of MABR led to silyl enol ethers in good yield.</jats:p>
Journal
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- Chemistry Letters
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Chemistry Letters 26 (6), 519-520, 1997-06-01
Oxford University Press (OUP)
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Keywords
Details 詳細情報について
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- CRID
- 1360565169062784768
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- NII Article ID
- 10002612314
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- NII Book ID
- AA00603318
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- ISSN
- 13480715
- 03667022
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- Data Source
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- Crossref
- CiNii Articles