Organoaluminum-Promoted Rearrangement of Epoxysilanes to <i>α</i>-Silylaldehydes

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  • Takashi Ooi
    Department of Chemistry, Graduate School of Science, Hokkaido UniversitySapporo
  • Toshitaka Kiba
    Department of Chemistry, Graduate School of Science, Hokkaido UniversitySapporo
  • Keiji Maruoka
    Department of Chemistry, Graduate School of Science, Hokkaido UniversitySapporo

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<jats:title>Abstract</jats:title> <jats:p>Selective rearrangement of epoxysilanes to α-silylaldehydes has been achieved with high efficiency by using exceptionally bulky oxygenophilic methylaluminum bis(4-bromo-2,6-di-tert-butylphenoxide) (MABR) as a stoichiometric reagent. Catalytic use of MABR led to silyl enol ethers in good yield.</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 26 (6), 519-520, 1997-06-01

    Oxford University Press (OUP)

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