Synthesis of Polynitrobenzene by Chemical Modification of Poly(N, N-dimethylaniline)

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著者

    • ZHENG Haipeng
    • Key Laboratory for Supramolecular Structure & Spectroscopy, and Department of Chemistry, Jilin University
    • ZHANG Ruifeng
    • Key Laboratory for Supramolecular Structure & Spectroscopy, and Department of Chemistry, Jilin University
    • SHEN Jiacong
    • Key Laboratory for Supramolecular Structure & Spectroscopy, and Department of Chemistry, Jilin University

抄録

Nitrification of poly(<I>N,N</I>-dimethylaniline)(PDMA) was carried out to synthesize a new kind of poly(phenylene)(PP) derivative–polynitrobenzene(PNB). Characterization of PNB and the determination of another product showed that in this reaction almost all the N,N-dimethyl groups on PDMA were replaced by the nitro groups without degradation. A possible mechanism of this special reaction has been put forward.

収録刊行物

  • Chemistry letters

    Chemistry letters 1997(7), 613-614, 1997-07

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10002612890
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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