Olefin-Insertion Reaction between the Carbonyls of Benzils ; Formation of 1, 4-Diketons by Michael Addition Catalyzed by Cyanide Ion

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Benzils (<B>1</B>) react with Michael addition acceptors (<B>2</B>) in the presence of cyanide ion as a catalyst to give 1,4-diketones (<B>3</B>), which are products of ethylene group insertion between the carbonyls of the benzils. The 1,4-diketones (<B>3</B>) are produced through the formation of the <I>O</I>-aroylmandelonitrile anion, followed by Michael addition and rearrangement of the aroyl group with decyanation.

収録刊行物

  • Chemistry letters

    Chemistry letters 1997(8), 697-698, 1997-08

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10002613400
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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