Preparation of m-Acylphenol Derivatives by the Reaction of Tricarbonyl(cyclohexadienone)iron Complex and Higher Order Cuprates

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著者

    • SOOHO Ban
    • Department of Chemistry, Graduate School of Science, The University of Tokyo
    • SAKURAI Hidehiro
    • Department of Chemistry, Graduate School of Science, The University of Tokyo
    • HAYASHI Yujiro
    • Department of Chemistry, Graduate School of Science, The University of Tokyo
    • NARASAKA Koichi
    • Department of Chemistry, Graduate School of Science, The University of Tokyo

抄録

Reaction of tricarbonyl[(2,3,4,5-η)-2,4-cyclohexadien-1-one]iron and higher order cuprates followed by the treatment with acetic anhydride and then with carbon monoxide affords tricarbonyl[(1,2,3,4-η)-1-acetoxy-5-<I>endo</I>-acyl-1,3-cyclohexadiene]iron complexes in good yield, which are converted to <I>meta</I>-acylphenol derivatives by the oxidation with trimethylamine <I>N</I>-oxide.

収録刊行物

  • Chemistry letters  

    Chemistry letters 1997(8), 699-700, 1997-08 

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10002613410
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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