Redox Behavior of Active Aldehydes Derived from Thiamin Coenzyme Analogs

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著者

    • NAKANISHI Ikuo
    • Department of Applied Chemistry, Faculty of Engineering, Osaka University
    • ITOH Shinobu
    • Department of Applied Chemistry, Faculty of Engineering, Osaka University
    • INOUE Hiroo
    • Department of Applied Chemistry, College of Engineering, Osaka Prefecture University

抄録

Redox behavior of active aldehydes of thiamin coenzyme models has been investigated using 3-benzylthiazolium salts and <I>o</I>-tolualdehyde in the presence of a base. The use of a sterically hindered aldehyde has precluded benzoin condensation of the active aldehydes, leading to the formation of relatively stable active aldehydes. The redox potentials of the active aldehydes have been determined by cyclic voltammetry for the first time, and they are sufficiently negative to reduce C<SUB>60</SUB> to the corresponding dianion (C<SUB>60</SUB><SUP>2−</SUP>).

収録刊行物

  • Chemistry letters

    Chemistry letters 1997(8), 707-708, 1997-08

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10002613470
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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