Chiral Recognition of Tetrahelicene Dicarboxylic Acid by Linear Dextrins

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  • Koji Kano
    Department of Molecular Science and Technology, Faculty of Engineering, Doshisha UniversityKyotanabe, Kyoto
  • Shigeru Negi
    Department of Molecular Science and Technology, Faculty of Engineering, Doshisha UniversityKyotanabe, Kyoto
  • Ryoko Takaoka
    Department of Molecular Science and Technology, Faculty of Engineering, Doshisha UniversityKyotanabe, Kyoto
  • Hisanobu Kamo
    Department of Molecular Science and Technology, Faculty of Engineering, Doshisha UniversityKyotanabe, Kyoto
  • Takashi Kitae
    Department of Molecular Science and Technology, Faculty of Engineering, Doshisha UniversityKyotanabe, Kyoto
  • Masahiko Yamaguchi
    Pharmaceutical Institute, Tohoku UniversityAoba, Sendai
  • Hitoshi Okubo
    Department of Chemistry, Graduate School of Science, Tohoku UniversityAoba, Sendai
  • Masahiro Hirama
    Department of Chemistry, Graduate School of Science, Tohoku UniversityAoba, Sendai

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<jats:title>Abstract</jats:title> <jats:p>Recognition of the helicity of 1,12-dimethylbenzo[c]phenanthrene-5,8-dicarboxylic acid (1) by linear oligosaccharides has been studied by 1H NMR spectroscopy and capillary zone electrophoresis. Both methods, clearly indicate that maltotetraose, maltopentaose, maltohexaose, and maltoheptaose selectively complex with the (M)-isomer of 1 as a guest through hydrogen-bonding interaction in water.</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 26 (8), 715-716, 1997-08-01

    Oxford University Press (OUP)

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