Charge-Transfer Complex of a New Acceptor Cyananilate with Tetramethyltetrathiafulvalene, (TMTTF)_2HCNAL

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著者

    • MD. BADRUZ Zaman
    • Department of Functional Molecular Science, The Graduate University for Advanced Studies
    • MORITA Yasushi
    • Department of Chemistry, Graduate School of Science, Osaka University
    • TOYODA Jiro
    • Department of Chemistry, Graduate School of Science, Osaka University
    • SAITO Gunzi
    • Department of Chemistry, Faculty of Science, Kyoto University
    • YONEYAMA Naoki
    • Department of Chemistry, Faculty of Science, Tokyo Institute of Technology
    • ENOKI Toshiaki
    • Department of Chemistry, Faculty of Science, Tokyo Institute of Technology

抄録

Cyananilic acid (H<SUB>2</SUB>CNAL) gave a charge-transfer complex with tetramethyltetrathiafulvalene, (TMTTF)<SUB>2</SUB>HCNAL, in which the acceptor forms a hydrogen-bonded ribbon arrangement and the donor forms a columnar stacking. The ionicity of the donor is estimated as +0.5. The electrical conductivity is 0.03 Scm<SUP>−1</SUP> with the activation energy of 0.05 eV. The magnetic spin susceptibility is described in terms of a one-dimensional antiferromagnet.

収録刊行物

  • Chemistry letters

    Chemistry letters 1997(8), 729-730, 1997-08

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10002613596
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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