The Effect of Packing Density on the Electron-Transfer Kinetics of an Azobenzenethiol Monolayer on Gold

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著者

    • SHAO Hui-Bo
    • Center for Intelligent Materials Research(CIMR), College of Chemistry and Molecular Engineering, Peking University
    • YU Hua-Zhong
    • Center for Intelligent Materials Research(CIMR), College of Chemistry and Molecular Engineering, Peking University
    • ZHAO Jian-Wei
    • Center for Intelligent Materials Research(CIMR), College of Chemistry and Molecular Engineering, Peking University
    • ZHANG Hao-Li
    • Center for Intelligent Materials Research(CIMR), College of Chemistry and Molecular Engineering, Peking University
    • LIU Zhong-Fan
    • Center for Intelligent Materials Research(CIMR), College of Chemistry and Molecular Engineering, Peking University

抄録

The effect of molecular packing density on the electron transfer kinetics in an azobenzene self-assembled monolayer on gold was investigated for the first time by controlling the assembling time. The apparent electron transfer rate constant (k<SUB>S</SUB>) showed a gradual decrease with increasing the molecular packing density, which can be well understood in terms of a structural inhibition occurred in the closely packed monolayer on the reduction/oxidation of azobenzene.

収録刊行物

  • Chemistry letters

    Chemistry letters 1997(8), 749-750, 1997-08

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10002613770
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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