Oxidative Reaction of 1, 5-Dithioniabicyclo[3. 3. 0]octane Bis(trifluoromethanesulfonate) with Diene Complexes of Zirconium and Tantalum : Synthesis of Cp_2Zr(OTf)_2(thf) and Cp(η^4-1, 3-butadiene)Ta(OTf)_2

この論文にアクセスする

この論文をさがす

著者

    • MASHIMA Kazushi
    • Department of Chemistry, Graduate School of Engineering Science, Osaka University
    • OSHIKI Toshiyuki
    • Department of Chemistry, Graduate School of Engineering Science, Osaka University
    • MATSUO Yutaka
    • Department of Chemistry, Graduate School of Engineering Science, Osaka University
    • TANI Kezuhide
    • Department of Chemistry, Graduate School of Engineering Science, Osaka University

抄録

Oxidative addition of a hypervalent organosulfur compound, 1,5-dithioniabicyclo[3.3.0]octane bis(trifluoromethanesulfonate) (<B>1</B>), to diene complexes of zirconium and tantalum, Cp<SUB>2</SUB>Zr(<I>η</I><SUP>4</SUP>-1,3-butadiene) and CpTa(<I>η</I><SUP>4</SUP>-1,3-butadiene)<SUB>2</SUB>, in THF resulted in the almost quantitative formation of bis(triflate) complexes of zirconium, Cp<SUB>2</SUB>Zr(OTf)<SUB>2</SUB>(thf) (<B>3</B>), and tantalum, CpTa(<I>η</I><SUP>4</SUP>-1,3-butadiene)(OTf)<SUB>2</SUB> (<B>5</B>), respectively.

収録刊行物

  • Chemistry letters  

    Chemistry letters 1997(8), 793-794, 1997-08 

    The Chemical Society of Japan

参考文献:  28件

参考文献を見るにはログインが必要です。ユーザIDをお持ちでない方は新規登録してください。

各種コード

  • NII論文ID(NAID)
    10002614083
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
ページトップへ