Magnetic Field Effect on Photochromism. Recombination of 2,3,4,5-Tetraphenylpyrrolyl Radicals

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  • Takako Nakai
    Department of Chemistry for Materials, Faculty of Engineering, Mie UniversityTsu
  • Masanao Tani
    Department of Chemistry for Materials, Faculty of Engineering, Mie UniversityTsu
  • Satoru Nishio
    Department of Chemistry for Materials, Faculty of Engineering, Mie UniversityTsu
  • Akiyoshi Matsuzaki
    Department of Chemistry for Materials, Faculty of Engineering, Mie UniversityTsu
  • Hiroyasu Sato
    Department of Chemistry for Materials, Faculty of Engineering, Mie UniversityTsu

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<jats:title>Abstract</jats:title> <jats:p>Photochromism of the dimer of 2,3,4,5-tetraphenylpyrrolyl radical consists of coloration by photochemical scission and decoloration by thermal recombination of radicals. Application of external magnetic field gave a pronounced retarding effect on the second-order recombination rate constant of escaped radicals.</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 26 (8), 795-796, 1997-08-01

    Oxford University Press (OUP)

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