Reaction of Silyl(carbonyl)iron Complexes with LiAlH_4 Giving Methylsilanes : Reduction of a Carbonyl Ligand and Coupling with a Silyl Group

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著者

    • TOBITA Hiromi
    • Department of Chemistry, Graduate School of Science, Tohoku University
    • SHIOZAWA Rie
    • Department of Chemistry, Graduate School of Science, Tohoku University
    • OGINO Hiroshi
    • Department of Chemistry, Graduate School of Science, Tohoku University

抄録

Treatment of CpFe(CO)<SUB>2</SUB>SiR<SUB>3</SUB> (R<SUB>3</SUB> = (<SUP><I>p</I></SUP>Tol)<SUB>2</SUB>H, (<SUP><I>p</I></SUP>Tol)<SUB>2</SUB>Me, MePh(1-Nap); 1-Nap = 1-naphthyl) with LiAlH<SUB>4</SUB> in ether or THF at room temperature gave CH<SUB>3</SUB>SiR<SUB>3</SUB> as a major product in moderate to high yield. The labeling experiments using LiAlD<SUB>4</SUB> and CpFe(<SUP>13</SUP>CO)<SUB>2</SUB>SiR(<SUP><I>p</I></SUP>Tol)<SUB>2</SUB> (R = H, Me) proved unambiguously that the carbonyl ligand is reduced with LiAlH<SUB>4</SUB> and coupled with the silyl group to give the methylsilane.

収録刊行物

  • Chemistry letters  

    Chemistry letters 1997(8), 805-806, 1997-08 

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10002614186
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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