Reaction of Silyl(carbonyl)iron Complexes with LiAlH_4 Giving Methylsilanes : Reduction of a Carbonyl Ligand and Coupling with a Silyl Group

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著者

    • TOBITA Hiromi
    • Department of Chemistry, Graduate School of Science, Tohoku University
    • SHIOZAWA Rie
    • Department of Chemistry, Graduate School of Science, Tohoku University
    • OGINO Hiroshi
    • Department of Chemistry, Graduate School of Science, Tohoku University

抄録

Treatment of CpFe(CO)<SUB>2</SUB>SiR<SUB>3</SUB> (R<SUB>3</SUB> = (<SUP><I>p</I></SUP>Tol)<SUB>2</SUB>H, (<SUP><I>p</I></SUP>Tol)<SUB>2</SUB>Me, MePh(1-Nap); 1-Nap = 1-naphthyl) with LiAlH<SUB>4</SUB> in ether or THF at room temperature gave CH<SUB>3</SUB>SiR<SUB>3</SUB> as a major product in moderate to high yield. The labeling experiments using LiAlD<SUB>4</SUB> and CpFe(<SUP>13</SUP>CO)<SUB>2</SUB>SiR(<SUP><I>p</I></SUP>Tol)<SUB>2</SUB> (R = H, Me) proved unambiguously that the carbonyl ligand is reduced with LiAlH<SUB>4</SUB> and coupled with the silyl group to give the methylsilane.

収録刊行物

  • Chemistry letters

    Chemistry letters 1997(8), 805-806, 1997-08

    The Chemical Society of Japan

参考文献:  10件中 1-10件 を表示

  • <no title>

    GLADYSZ J. A.

    Adv. Organometal. Chem. 20, 1, 1982

    被引用文献1件

  • <no title>

    TREICHEL P. M.

    Inorg. Chem. 6, 1328, 1967

    被引用文献2件

  • <no title>

    WONG A.

    J. Organomet. Chem. 210, 395, 1981

    被引用文献1件

  • <no title>

    Cerveau G.

    J. Organomet. Chem. 135, 373, 1977

    被引用文献2件

  • <no title>

    COLOMER E.

    J. Organomet. Chem. 133, 159, 1977

    被引用文献2件

  • <no title>

    COLOMER E.

    J. Chem. Soc., Chem. Commun. 1976, 175

    被引用文献1件

  • <no title>

    COLOMER E.

    Inorg. Chem. 18, 695, 1979

    被引用文献1件

  • <no title>

    CERVEAU G.

    J. Organomet. Chem. 236, 33, 1982

    被引用文献1件

  • <no title>

    WEKEL H. -U.

    J. Organomet. Chem. 264, C10, 1984

    被引用文献2件

  • <no title>

    SAKAKI S.

    J. Am. Chem. Soc. 115, 2373, 1993

    被引用文献3件

各種コード

  • NII論文ID(NAID)
    10002614186
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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