Ionic and Radical Substitution in Cobaltadithiolene Ring Induced by Dibenzoyl Peroxide

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著者

    • SUGIMORI Akira
    • Department of Chemistry, Faculty of Science and Technology, Sophia University
    • YANAGI Kumiko
    • Department of Chemistry, Faculty of Science and Technology, Sophia University
    • HAGINO Genjiro
    • Department of Chemistry, Faculty of Science and Technology, Sophia University
    • TAMADA Minako
    • Department of Chemistry, Faculty of Science and Technology, Sophia University
    • KAJITANI Masatsu
    • Department of Chemistry, Faculty of Science and Technology, Sophia University
    • AKIYAMA Takeo
    • Department of Chemistry, Faculty of Science and Technology, Sophia University

抄録

The reaction of (<I>η</I><SUP>5</SUP>-cyclopentadienyl)(1,2-ethenedithiolato)cobalt(III) complexes with dibenzoyl peroxide at moderate temperature (40 °C) brings about the substitution of a benzoyloxy group for a hydrogen in the cobaltadithiolene ring in an ionic mechanism. At 110 °C in a toluene solution, the substitution of a benzyl group for a hydrogen in the cobaltadithiolene ring in a radical mechanism occurs competitively with benzoyloxylation.

収録刊行物

  • Chemistry letters  

    Chemistry letters 1997(8), 807-808, 1997-08 

    The Chemical Society of Japan

参考文献:  15件

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各種コード

  • NII論文ID(NAID)
    10002614197
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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