Ionic and Radical Substitution in Cobaltadithiolene Ring Induced by Dibenzoyl Peroxide

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著者

    • SUGIMORI Akira
    • Department of Chemistry, Faculty of Science and Technology, Sophia University
    • YANAGI Kumiko
    • Department of Chemistry, Faculty of Science and Technology, Sophia University
    • HAGINO Genjiro
    • Department of Chemistry, Faculty of Science and Technology, Sophia University
    • TAMADA Minako
    • Department of Chemistry, Faculty of Science and Technology, Sophia University
    • KAJITANI Masatsu
    • Department of Chemistry, Faculty of Science and Technology, Sophia University
    • AKIYAMA Takeo
    • Department of Chemistry, Faculty of Science and Technology, Sophia University

抄録

The reaction of (<I>η</I><SUP>5</SUP>-cyclopentadienyl)(1,2-ethenedithiolato)cobalt(III) complexes with dibenzoyl peroxide at moderate temperature (40 °C) brings about the substitution of a benzoyloxy group for a hydrogen in the cobaltadithiolene ring in an ionic mechanism. At 110 °C in a toluene solution, the substitution of a benzyl group for a hydrogen in the cobaltadithiolene ring in a radical mechanism occurs competitively with benzoyloxylation.

収録刊行物

  • Chemistry letters

    Chemistry letters 1997(8), 807-808, 1997-08

    The Chemical Society of Japan

参考文献:  15件中 1-15件 を表示

  • <no title>

    SCHRAUZER G. N.

    Acc. Chem. Res. 2, 72, 1969

    被引用文献6件

  • <no title>

    MCCLEVERTY J. A.

    Prog. Inorg. Chem. 10, 49, 1969

    被引用文献7件

  • <no title>

    BURNS R. P.

    Adv. Inorg. Chem. Radiochem. 22, 303, 1979

    被引用文献8件

  • <no title>

    MUELLER-WESTERHOFF U. T.

    Comprehensive Coordination Chemistry 2, 545, 1987

    被引用文献4件

  • <no title>

    SHIGIMORI A.

    Yuki Gosei Kagaku Kyokai Shi 48, 788, 1990

    被引用文献1件

  • <no title>

    KAJITANI M.

    J. Am. Chem. Soc. 118, 489, 1996

    被引用文献5件

  • <no title>

    SUGIMORI A.

    Organometallics 15, 5564, 1996

    被引用文献2件

  • <no title>

    BOUILLON G.

    The Chemistry of Functional Groups Peroxides 279, 1983

    被引用文献1件

  • <no title>

    TOKUMARU K.

    Bull. Chem. Soc. Jpn. 36, 333, 1963

    被引用文献2件

  • <no title>

    TOKUMARU K.

    Yuuki Gosei Kagaku Kyoukai Shi 21, 164, 1963

    被引用文献1件

  • <no title>

    OAE Cf. S.

    Tetrahedron 28, 3203, 1972

    被引用文献1件

  • <no title>

    BATTEN J. J.

    J. Chem. Soc. 1956, 2948

    被引用文献1件

  • <no title>

    WALLING C.

    J. Am. Chem. Soc. 80, 228, 1958

    被引用文献1件

  • <no title>

    DENNEY D. B.

    J. Am. Chem. Soc. 82, 1389, 1960

    被引用文献1件

  • <no title>

    HORNER L.

    Liebigs Ann. Chem. 602, 135, 1957

    被引用文献1件

各種コード

  • NII論文ID(NAID)
    10002614197
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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