4, 5-Diiodo-4', 5'-ethylenedioxytetrathiafulvalene and Its Metallic Radical Salts

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著者

    • OGURA Eiji
    • Department of Chemistry, Faculty of Science, Tokyo Metropolitan University
    • IKEMOTO Isao
    • Department of Chemistry, Faculty of Science, Tokyo Metropolitan University
    • IYODA Masahiko
    • Department of Chemistry, Faculty of Science, Tokyo Metropolitan University

抄録

4,5-Diiodo-4′,5′-ethylenedioxy-TTF (EDO-TTFI<SUB>2</SUB>) was synthesized in moderate yield by the reaction of EDO-TTF with LDA, followed by quenching with CF<SUB>3</SUB>(CF<SUB>2</SUB>)<SUB>5</SUB>I. Although EDO-TTF contains electron-withdrawing iodine as the substituent, this compound has a similar donor ability to BEDT-TTF. The radical-cation salt (EDO-TTFI<SUB>2</SUB>)<SUB>2</SUB>·ClO<SUB>4</SUB> shows a metallic conductivity down to 50 K, reflecting the strong I···O interaction.

収録刊行物

  • Chemistry letters

    Chemistry letters 1997(8), 817-818, 1997-08

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10002614273
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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